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Best method to purify proteins that are bound in immune complexes???

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Topic Started by ParasiteDude13
on 7/3/2012 11:47 AM   
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Hello all!  I hope that I am posting this in the correct place.  This is my first post here!  Hopefully someone has some suggestions/critiques that can help me out.  I mostly would just like to see if anyone else knows of good, alternative ways to purify and isolate parasite (or other organisms) secreted proteins bound in host immune complexes.

I first centrifuge the whole serum through 5% PEG-6000 at 3000RPM followed by two additional washes with 2.5% PEG-6000 to remove unwanted serum components. The pellet is then resuspended in PBS buffer. I have seen this protocol in a few papers, and it seems to fit for the purposes of my project. 

Next, the resuspended sample is put through an affinity column with Protein A sepharose beads.  My thinking is that the IgGs that are bound in immune complexes will stick to the protein A beads and the whole complex will stay on the column during subsequent washes.

I then elute with a strong acid (pH 2.8) and collect fractions.  I check the OD280 NanoDrop reading for each fraction to see when the immune complex proteins come off the column, before pooling the fractions and concentrating the sample
 
I believe that the sample could then be run on a SDS-PAGE gel without any reducing agents.  This would theoretically keep all of the, now free, whole antibodies from entering the gel due to the unbroken disulfide bonds within each antibody.  The molecular weight would be to high for them to run with the proteins of interest.

The ultimate goal of my experiment here is to send the collected proteins out for mass spectrometry, to identify which proteins can be found in vivo.   The problem is that I just sent my sample to have mass spec done and the results don't show any parasite proteins whatsoever.  Does anyone have a suggestion on how I might go about purifying these proteins from serum to send for mass spec???


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ARGERINE
India

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Posted By ARGERINE
on 7/10/2012 11:33 AM   
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 Hi 
PEG may be able to break bonds b/w Ag-Ab complex. Try purification of IgG fraction directly using ProteinA/G column and then elute using acidic pH. Neutralize and follow it up with a reducing SDS glycine/ tricine PAGE.
Remember that Proteins that you are expecting must be in low cncentration and you need to filter that from noise of IgG signals through MS. Use silver staining for more sensitive output . Even though IgG bands may not correspond to the protein/peptide of yr interest, they may appear at multiple levels while you perform MS.

FYI: I have worked with plasma for years and It's a dauting task that you have undertaken. Be patient.

All the best

Gaganjot Singh Truth seems so closer now......



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